1202.4644 (Emmanuel Baudin)

Magic composite pulses    [PDF]

Emmanuel Baudin

I describe composite pulses during which the average dipolar interactions
within a spin ensemble are controlled while realizing a global rotation. The
construction method used is based on the average Hamiltonian theory and rely on
the geometrical properties of the spin-spin dipolar interaction only. I present
several such composite pulses robust against standard experimental defects in
NRM: static or radio-frequency field miscalibration, fields inhomogeneities.
Numerical simulations show that the magic sandwich pulse sequence, a pulse
sequence that reverse the average dipolar field while applied, is plagued by
defects originating from its short initial and final \pi/2 radio-frequency
pulses. Using the magic composite pulses instead of \pi/2 pulses improves the
magic sandwich effect. A numerical test using a classical description of NMR
allows to check the validity of the magic composite pulses and estimate their
efficiency.

View original: http://arxiv.org/abs/1202.4644