Pierre-François Loos, Peter M. W. Gill
We introduce a new paradigm for finite and infinite strict-one-dimensional uniform electron gases. In this model, $n$ electrons are confined to a ring and interact via a bare Coulomb operator. In the high-density limit (small-$r_s$, where $r_s$ is the Seitz radius), we find that the reduced correlation energy is $\Ec(r_s,n) = \eps^{(2)}(n) + O(r_s)$, and we report explicit expressions for $\eps^{(2)}(n)$. In the thermodynamic (large-$n$) limit of this, we show that $\Ec(r_s) = - \pi^2/360 + O(r_s)$. In the low-density (large-$r_s$) limit, the system forms a Wigner crystal and we find that $\Ec(r_s) = -[\ln(\sqrt{2\pi})-3/4]\,r_s^{-1} + 0.359933\,r_s^{-3/2} + O(r_s^{-2})$. Using these results, we propose a correlation functional that interpolates between the high- and low-density limits. The accuracy of the functional for intermediate densities is established by comparison with diffusion Monte Carlo results. Application to a non-uniform system is also reported.
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http://arxiv.org/abs/1207.0908
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