Wednesday, January 16, 2013

1301.3213 (Dmitry N. Saulov et al.)

Modified Associate Formalism without Entropy Paradox: Part I. Model

Dmitry N. Saulov, Igor G. Vladimirov, A. Y. Klimenko
A Modified Associate Formalism is proposed for thermodynamic modelling of solution phases. The approach is free from the entropy paradox described by L\"{u}ck et al. (Z. Metallkd. 80 (1989) pp. 270--275). The model is considered in its general form for an arbitrary number of solution components and an arbitrary size of associates. Asymptotic behaviour of chemical activities of solution components in binary dilute solutions is also investigated.
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